Re: Isshin Kurosaki?
Urahara said that he gave up his Shinigami powers 20 years ago, which wouldn't fit if he stepped back as a captain 100 years ago. Also, it is implied that he doesn't know the true origin of the Vizards and that he only has heard of them, and furthermore, Shinji didn't recognize his reiatsu, which he should have if he was a captain in his time.
It could be that he had been the captain of 10th Squad before Toshiro Hitsugaya, as it would fit the fact that he, as mentioned before, lost his Shinigami powers 20 years ago, and that Hitsugaya became a captain not long after that.
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